CURRICULUM VITAE

Assoc.Prof.Dr. Bülent Düz

Chemistry Department, Inorganic Chem. Div., Hacettepe University, Ankara, 1997

THESIS

MSc:
University/Year: Hacettepe University, 1990
Faculty: Science
Department and Title of Thesis: Chemistry; Investigation of Ring-opening metathesis polymerization reactions with W(CO)6-CCl4 / hn catalytic system, MSc Thesis, Hacettepe University, Ankara, 70 p.

PhD:
University/Year: Hacettepe University, 1997
Faculty: Science
Department and Title of Thesis: Chemistry; Investigation of Olefin Metathesis Reactions by Electrochemically Generated catalysts, PhD Thesis, Hacettepe University, Ankara, 120 p

*Novel Metathesis catalyst Systems and application on olefin metathesis reactions

* Synthesis of Metathetic polymers (unsaturated polymers via ROMP and ADMET Polymerizations) and characterizations

*Metal Carbene Generation by reaction of atomic carbon with transition metal salts  and their activities  on olefins

* Electrochemically generated  catalyst systems

Hacettepe University, Faculty of Science, Department of Chemistry, Honor Award, 2007

PUBLICATIONS

A.  Articles Published in International (SCI)  Journals

A1. Dereli O., Düz B., Zümreoğlu-Karan B*. and İmamoğlu Y*, “Electrochemically generated tungsten-based active species as catalyst for metathesis-related reactions:1. Acyclic diene metathesis polymerization of 1,9-decadiene,” Applied Organometallic Chemistry, 17, 23-27 (2003).

A2. Çetinkaya S., Düz B. and İmamoğlu Y*, “Electrochemically reduced tungsten-based active species as catalyst for cross-metathesis reactions:cross metathesis of non functionalized olefins,” Applied Organometallic Chemistry, 17, 232-235 (2003).

A3. Sevin F., Sökmen İ., Düz B. and Shevlin P.B*, “Trapping of a cycloheptatetraene in the reaction of atomic carbon with phenol,” Tetrahedron Letters, 44, 3405-3047 (2003).

A4. Düz B., Pekmez K., İmamoğlu Y*., Süzer Ş. and Yıldız A. “Electrochemically generated catalyst system with increased specificity and efficiency for olefin metathesis” Journal of Organometallic Chemistry, 684, 77-81 (2003)

A5. Çetinkaya S., Düz B. and İmamoğlu Y*. “Electrochemically reduced tungsten-based active species as catalyst for cross-metathesis reactions.Cross-metathesis of erucic acid with 2-octene” Applied Organometallic Chemistry, 18, 19-22 (2004).

A6. Dereli O., Düz B., Zümreoğlu-Karan B*. and İmamoğlu Y*, “Electrochemically generated tungsten-based active species as catalyst for metathesis-related reactions:2. ring-opening metathesis polymerization (ROMP) of norbornene,” Applied Organometallic Chemistry, 18, 130-134 (2004).

A7. Karabulut S., Çetinkaya S., Düz B and İmamoglu Y*, “Ring-opening metathesis polymerization (ROMP) of cyclododecene using electrochemically reduced tungsten-based”  Applied Organometallic Chemistry, 18, 375-379 (2004).

A8. Çetinkaya S., Karabulut S., Düz B and İmamoglu Y*, “Synthesis and characterization of polyoctenamer with WCl6-e—AlCH2Cl2 catalyst system via ring-opening metathesis polymerization”  Applied Organometallic Chemistry, 19, 347-351 (2005).

A9. Dereli O., Aydoğdu C., Düz B. and İmamoğlu Y*, “Application of electrochemically generated Mo-based catalyst system to the ROMP of norbornene and a comparison with the W-analogue”  Applied Organometallic Chemistry, 19, 834-840 (2005).

A10. Dereli O., Düz B. and İmamoğlu Y*, “The WCl6–e−–Al–CH2Cl2 catalyzed polypentenamer formation via ring-opening metathesis polymerization (ROMP) ”  European Polymer Journal, 42, 368-374 (2006).

A11. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y*, “Synthesis and characterization of Ge- and Sn-containing ADMET polymers” Journal of Molecular Catalysis A: Chemical,  254, 186-191 (2006).

A12. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y*, “Metal-containing polymers synthesized via acyclic diene metathesis (ADMET) polymerization using electrochemically reduced tungsten-based catalyst : Polycarbogermanes” Journal of Inorganic and Organometallic Polymers and Materials, 16, 115-122 (2006).

A13. Düz B*., Yüksel D., Ece A and Sevin F*, “The first example of tungsten-based carbene generation from WCl6 and atomic carbon and its use in olefin metathesis” Tetrahedron Letters, 47, 5167-5170 (2006).

A14. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y*, “Metal-containing polymers synthesized via acyclic diene metathesis (ADMET) polymerization using electrochemically reduced tungsten-based catalyst : Polycarbosilanes” Journal of Inorganic and Organometallic Polymers and Materials, 17,517-523 (2007).

B. BOOK CHAPTERS

B1. Düz B., Bozkurt Ç. and İmamoğlu Y.,  “Photocatalytic ring-opening polymerization of norbornene, norbornadiene and cyclopentene” Olefin Metathesis and Polymerization Catalyst, NATO ASI Series C, Vol., 326 Kluver, Dortrecht, 559 (1990).

B2. Düz B., Pekmez K., İmamoğlu Y., Süzer Ş. and Yıldız A.,  “Electrochemically generated tungsten-based catalyst for olefin metathesis” ROMP and Related Chemistry State of the Art and Visions for the New Century, NATO ASI, Polonica-Zdroj, Sept. 3-15 Poland, 2000.

B3. Düz B., Melkuç N. and İmamoğlu Y., “Metathetic degradation of 1,4-polybutadiene by electrochemically generated WCl6-based catalyst system” ROMP and Related Chemistry State of the Art and Visions for the New Century, NATO ASI, Polonica-Zdroj,  Sept. 3-15, Poland, 2000.

B4. Aydoğdu C., Düz B., İmamoğlu Y. and Süzer Ş., “Investigation of nature of the active species and carbene formation in photocatalytic metathesis reactions” ROMP and Related Chemistry State of the Art and Visions for the New Century, NATO ASI, Polonica-Zdroj, Sept. 3-15, Poland, 2000.

B5. Ece A., Elbistan C.K.,  Düz B and Sevin F., “Molybdenum-based carbene generation by MoCl5 and atomic carbon reaction for olefin metathesis” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006.

B6. Dereli O., Aydoğdu C., Düz B. and İmamoğlu Y., “Electro-induced Mo-based catalyst system initiated ROMP reactions” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006.

B7. Karabulut S., Aydoğdu C.,  Düz B. and İmamoğlu Y., “Synthesis of Si, Ge and Sn Containing unsaturated polymers by acyclic diene metathesis(ADMET) polymerization using an electrochemically generated catalyst” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006.

C. PRESENTATIONS (INTERNATIONAL)

C1. Düz B*., Aydoğdu C. and İmamoğlu Y. “Application of uniform-macroporous polysytrene particles as support in W(CO)6-CCl4/hn photocatalytic olefin metathesis system”, Novel Metathesis Chemistry Designing Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Materials Applications, eds. Y. İmamoğlu and L. Bencze, NATO ASI Series II, Vol 122. Kluwer Academic Publishers: Dordrecht 2003, 295-301.

C2. Dereli O., Düz B. and İmamoğlu Y. “Acyclic diene metathesis (ADMET) polymerization by electrochemically generated tungsten-based active catalyst system: Optimization of reaction conditions”, Novel Metathesis Chemistry Designing Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Materials Applications, eds. Y. İmamoğlu and L. Bencze, NATO ASI Series II, Vol 122. Kluwer Academic Publishers: Dordrecht 2003, 243-247.

C3. Çetinkaya S., Düz B. and İmamoğlu Y. “Study of the stability and activity of electrochemically produced tungsten-based metathesis catalyst with symetrical alkenes”,  Novel Metathesis Chemistry Designing Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Materials Applications, eds. Y. İmamoğlu and L. Bencze, NATO ASI Series II, Vol 122. Kluwer Academic Publishers: Dordrecht 2003, 160-171.

C4. Sevin F. and Düz B. “Reactions of atomic carbon with 2-norbornene”, Novel Metathesis Chemistry Designing Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Materials Applications, eds. Y. İmamoğlu and L. Bencze, NATO ASI Series II, Vol 122. Kluwer Academic Publishers: Dordrecht 2003, 303-308.

C5. Sevin F. and Düz B. “Intramolecular trapping of strained bicyclic allene in carbon atom reactions”, Novel Metathesis Chemistry Designing Well-Defined Initiator Systems for Specialty Chemical Synthesis, Tailored Polymers and Advanced Materials Applications, eds. Y. İmamoğlu and L. Bencze, NATO ASI Series II, Vol 122. Kluwer Academic Publishers: Dordrecht 2003, 309-312.

C6. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y., “ADMET polymerization activities of electrochemically reduced W-based active species for Ge and Sn containing dienes” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006. in press.

C7. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y., “A study on the reactivity of WCl6-e--Al-CH2Cl2  with the silicon containing dienes” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006. in press.

C8. Dereli O., Aydoğdu C., Düz B. and İmamoğlu Y., “Electro-induced Mo-based catalyst system initiated ROMP reactions” New Frontiers in Metathesis: From Nanostructure Design to Sustainable Technologies from Synthesis of Advanced Materials  NATO-ASI, Antalya Sept. 4-16, Turkey, 2006.

D. PRESENTATIONS (NATIONAL)

D1. Düz B., Bozkurt Ç., İmamoğlu Y., “W(CO)6-CCl4/hn katalizör sistemiyle norbornenin halka açılımı metatez polimerizasyonu,” IX. Kimya ve Kimya Mühendisliği Sempozyum, KİMYA 93, 20-24 Eylül 1993, Karadeniz Teknik Üniversitesi, Trabzon.

D2. Düz B., Pekmez K., İmamoğlu Y., Yıldız A., “Electrokimyasal olarak üretilen katalizör ile metatez tepkimelerinin incelenmesi,” XI. Ulusal Kimya Kongresi, KİMYA 1997, 16-20 Haziran 1997, Yüzüncü Yıl Üniversitesi, Van.

D3. Aydoğdu C., Düz B., İmamoğlu Y., Süzer Ş., “W(CO)6-CCl4/hn katalizör sisteminde oluşan tungsten kompleksinin yapısı ve olefin metatez tepkimelerindeki rolü,” 12. Ulusal Kimya Kongresi, KİMYA 1998, 7-11 Eylül 1998, Trakya Üniversitesi, Edirne.

D4. Aydoğdu C., Düz B., İmamoğlu Y., “ Fotokimyasal metatez tepkimelerini katalizleyen tungsten-alkiliden komplekslerinin oluşumunun incelenmesi,” 12. Ulusal Kimya Kongresi, KİMYA 1998, 7-11 Eylül 1998, Trakya Üniversitesi, Edirne.

D5. Dereli O., Düz B., İmamoğlu Y., “Elektrokimyasal yolla elde edilen tungsten bazlı katalizör sistemi ile halka açılımı metatez polimerizasyonu,” XV. Ulusal Kimya Kongresi, KİMYA 2001,4-7 Eylül 2001, Boğaziçi Üniversitesi, İstanbul.

D6. Dereli O., Düz B., İmamoğlu Y., “WCl6’ ün elektrokimyasal indirgenmesiyle oluşturulan katalizör sistemi ile asiklik dienlerin metatez (ADMET) polimerizasyonu,” XV. Ulusal Kimya Kongresi, KİMYA 2001,4-7 Eylül 2001, Boğaziçi Üniversitesi, İstanbul.
D7. Karabulut S.,Aydoğdu C., Düz B. and İmamoğlu Y., Synthesis of Organometallic Polymers via an Electrochemically Produced Catalyst System 1. Acyclic Diene Metathesis Polymerization (ADMET) of Germanium Conatining Monomers, XIX. National Chemistry Congress, Ege University, Kuşadası, TURKEY.

D8. Karabulut S., Aydoğdu C., Düz B. and İmamoğlu Y., Synthesis of Organometallic Polymers via an Electrochemically Produced Catalyst System 2. Acyclic Diene Metathesis Polymerization (ADMET) of Tin Conatining Monomers, XIX. National Chemistry Congress, Ege University, Kuşadası, TURKEY.

E. PROJECTS

E1. “Elektrokimyasal Yöntemle Olefin Metatez Tepkimelerinde Aktif  Katalizör sentezi,  Yapısının Aydınlatılması ve Olefin Metatez Tepkimelerine Uygulanması”, TÜBİTAK Projesi, TBAG-1609 (197T053), Araştırmacı, 1997-2000.

E2. “Olefin Metatez Tepkimelerinde Aktif Katalizörün Elrktrokimyasal Sentezi Yapısı ve Uygulamaları” H.Ü. Araştırma Fonu, Devlet Planlama Teşkilatı Araştırma Projesi, 98 K 121 720, Araştırmacı, 1998-2001.

E3. “Metatez Kataizörü Tungsten Ariloksit Komplekslerinin sentezi, Polistiren Bazlı Eş Mikrokürelere İmmobilizasyonu ve Uygulamaları” TÜBİTAK Projesi, TBAG-2147(102T040),Proje Yöneticisi, 2002-2004.

E4. “Elektrokimyasal Yöntemle Elde Edilen Katalizör Sistemi ile Asiklik ve Fonksiyonel Grup İçeren Olefinlerin Çapraz Metatezi” TÜBİTAK Projesi, TBAG-2148 (102T039), Araştırmacı, 2002-2004.

E5. “Atomik Karbonun Fenol ve Norbornen ile Reaksiyonları ” TÜBİTAK Projesi, TBAG-AY/284(102T140) TÜBİTAK, Araştırmacı, 2002- 2004.

E6. “İnorganik ve Polimerik Malzemelerin Isısal Analiz Teknikleri ile İncelenmesi”,  H.Ü. Araştırma Fonu Güdümlü Araştırma Projesi, 02G03, Araştırmacı, 2002-2004.

E7. “Farmokinetik Parametreler Üzerine İyontoforez ve Fonoforez Tekniklerin Etkileri” , H.Ü. Araştırma Fonu Araştırma Projesi, 0002401001, Araştırmacı, 2002- 2004.

E8. “Atomik Karbonun Anilin ile Reaksiyonları” TÜBİTAK Projesi TBAG-AY/284 (102T142) Araştırmacı, 2005-2006

E9. “Metatez Polimerizasyon Reaksiyonları ile Metal İçeren Doymamış Polialkenamerlerin sentezi” TÜBİTAK Projesi, TBAG-104T344, Araştırmacı, 2004- 2006.

E10. “Metal içeren Monomerlerin Sentezi ve Elektrokimyasal Yöntemle Üretilen Katalizör Sistemi ile Halka Açılımı metatez Polimerizasyonu” H.Ü. Araştırma Fonu Kapsamlı Araştırma Projesi, 04D09601001, Araştırmacı, 2005- devam etmektedir.

E11. “Nükleer Magnetik Rezonans Çalışması” H.Ü. Araştırma Fonu Alt Yapı Araştırma Projesi, 04A601011, Araştırmacı, 2005- devam etmektedir.

E12. “Asiklik Dien Metatezi ile Organometalik Polimerlerin sentezi ve Yapılarının Aydınlatılması” H.Ü. Araştırma Fonu Alt Yapı Araştırma Projesi, 04A601014, Araştırmacı, 2006- devam etmektedir.

E13. “Atomik Karbon ve Geçiş Metal Tuzları İle Metal-Karben Oluşumu: Olefin Metatez Tepkimelerindeki Katalitik Aktivitesi” TÜBİTAK Projesi , TBAG-104T402,Araştırmacı, 2006-2007.